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Issue 10, 2018, Issue in Progress
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Synthesis of CHF2-substituted 3-azabicyclo[3.1.0]hexanes by photochemical decomposition of CHF2-pyrazolines

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Abstract

A practical synthesis of CHF2-substituted 3-azabicyclo[3.1.0]hexanes was developed for the first time. The key step was photochemical decomposition of CHF2-substituted pyrazolines. This protocol has the advantages of simple operation, and mild conditions, as well as excellent functional group tolerance, giving the desired products in moderate to excellent yields.

Graphical abstract: Synthesis of CHF2-substituted 3-azabicyclo[3.1.0]hexanes by photochemical decomposition of CHF2-pyrazolines

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Supplementary files

Article information


Submitted
08 Dec 2017
Accepted
23 Jan 2018
First published
29 Jan 2018

This article is Open Access

RSC Adv., 2018,8, 5114-5118
Article type
Paper

Synthesis of CHF2-substituted 3-azabicyclo[3.1.0]hexanes by photochemical decomposition of CHF2-pyrazolines

Y. Zheng, X. Yu, S. Lv, P. K. Mykhailiuk, Q. Ma, L. Hai and Y. Wu, RSC Adv., 2018, 8, 5114
DOI: 10.1039/C7RA13141K

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