Issue 17, 2018
From the journal:

Organic Chemistry Frontiers

Bromide-catalyzed electrochemical trifluoromethylation/cyclization of N-arylacrylamides with low catalyst loading†

Yang-Ye Jiang,a   Gui-Yuan Dou,a   Kun Xua  and  Cheng-Chu Zeng ORCID logo *a  

* Corresponding authors

a Beijing Key Laboratory of Environmental and Viral Oncology, College of Life Science & Bioengineering, Beijing University of Technology, Beijing 100124, China
E-mail: zengcc@bjut.edu.cn

Abstract

The electrochemical trifluoromethylarylation of N-arylacrylamides catalyzed by bromide is described. The synthetic utility of this methodology is demonstrated by transition metal-free and external oxidant-free conditions, and low catalyst loading.

Graphical abstract: Bromide-catalyzed electrochemical trifluoromethylation/cyclization of N-arylacrylamides with low catalyst loading

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Article information

DOI
https://doi.org/10.1039/C8QO00645H
Article type
Research Article
Submitted
30 Jun 2018
Accepted
27 Jul 2018
First published
30 Jul 2018

Org. Chem. Front., 2018,5, 2573-2577

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Bromide-catalyzed electrochemical trifluoromethylation/cyclization of N-arylacrylamides with low catalyst loading

Y. Jiang, G. Dou, K. Xu and C. Zeng, Org. Chem. Front., 2018, 5, 2573 DOI: 10.1039/C8QO00645H

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