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Issue 17, 2018
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Visible-light-mediated radical arylthiodifluoromethylation of isocyanides with fluorinated 2-pyridyl sulfones

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Abstract

A novel class of shelf-stable and easily scalable arylthiodifluoromethyl 2-pyridyl sulfone derivatives was developed as powerful arylthiodifluoromethylation reagents, which allow efficient radical arylthiodifluoromethylation of various isocyanides to form phenanthridines and isoquinolines in good to excellent yields.

Graphical abstract: Visible-light-mediated radical arylthiodifluoromethylation of isocyanides with fluorinated 2-pyridyl sulfones

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Submitted
30 Jun 2018
Accepted
26 Jul 2018
First published
27 Jul 2018

Org. Chem. Front., 2018,5, 2568-2572
Article type
Research Article

Visible-light-mediated radical arylthiodifluoromethylation of isocyanides with fluorinated 2-pyridyl sulfones

J. Wei, D. Gu, S. Wang, J. Hu, X. Dong and R. Sheng, Org. Chem. Front., 2018, 5, 2568
DOI: 10.1039/C8QO00644J

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