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One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides

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Abstract

A new and practical approach to α-dithioacetal/α-diselenoacetal amides has been developed, combining sequential functionalization of amides and a C–C bond cleavage strategy. In this reaction, various α-dithioacetal/α-diselenoacetal amides from 3-oxo-butanamides were prepared in one step with good regioselectivity and functional group tolerance.

Graphical abstract: One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides

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Publication details

The article was received on 28 Apr 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Research Article
DOI: 10.1039/C8QO00435H
Citation: Org. Chem. Front., 2018, Advance Article
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    One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides

    J. Zou, Y. Wang, L. Huang, Y. Jiang, J. Chen, L. Zhu, Y. Yang, Y. Feng, X. Peng and Z. Wang, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00435H

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