SCHEDULED MAINTENANCE
A facile formal ene reaction of trisubstituted silylallenes with triplet molecular oxygen involving the cleavage of a H–C(sp2) bond has been described. For this formal ene reaction, the silyl substituent was found to be critical to induce peroxide formation. DFT calculations clearly show the dramatic weakening of the allenic C(sp2)–H bond by the α-silyl group.
Y. Xia, N. Lee, V. R. Sabbasani, S. Gupta and D. Lee, Org. Chem. Front., 2018, 5, 2542 DOI: 10.1039/C8QO00390D
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
