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Abstract | Cited by

A facile synthesis of carbo- and heterocycles via Fe(III)-catalyzed alkene hydrofunctionalization has been developed. Various alkenes bearing a leaving group could convert to alkyl radicals through hydrogen atom transfer (HAT), and then serve as cyclization dipoles for accessing carbo- and heterocycles. The synthetic utility was further demonstrated by the synthesis of tetracyclic carbocycles from isopregol.

Graphical abstract: Facile synthesis of carbo- and heterocycles via Fe(iii)-catalyzed alkene hydrofunctionalization

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