Issue 1, 2018
From the journal:

Organic Chemistry Frontiers

The regioselective synthesis of 2-phosphinoylindoles via Rh(iii)-catalyzed C–H activation†

Huanan Wang,a   Shuaiqi Li,a   Baiquan Wang ORCID logo abc  and  Bin Li ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: nklibin@nankai.edu.cn

b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, P. R. China

c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, shanghai 200032, P. R. China

Abstract

The redox-neutral annulation of N-nitrosoanilines with 1-alkynylphosphine oxides under rhodium catalysis was achieved. This step-economical protocol affords 2-phosphinoylindoles in excellent regioselectivity with good functional group tolerance.

Graphical abstract: The regioselective synthesis of 2-phosphinoylindoles via Rh(iii)-catalyzed C–H activation

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Article information

DOI
https://doi.org/10.1039/C7QO00746A
Article type
Research Article
Submitted
22 Aug 2017
Accepted
21 Sep 2017
First published
22 Sep 2017

Org. Chem. Front., 2018,5, 88-91

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The regioselective synthesis of 2-phosphinoylindoles via Rh(III)-catalyzed C–H activation

H. Wang, S. Li, B. Wang and B. Li, Org. Chem. Front., 2018, 5, 88 DOI: 10.1039/C7QO00746A

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