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A colorless semi-aromatic polyimide derived from a sterically hindered bromine-substituted dianhydride exhibiting dual fluorescence and phosphorescence emission

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Abstract

Colorless, transparent, and environmentally stable polymer films with large luminescence Stokes shift are in demand for down-conversion of solar UV radiation. To develop such a polymer film that exhibits phosphorescence at room-temperature with a large Stokes shift and excellent thermal stability, a semi-aromatic polyimide (DBrBP-PI) was newly synthesized using a biphenyltetracarboxylic dianhydride substituted with two bromine (Br) atoms. Thin films of DBrBP-PI were completely colorless because of effective suppression of the aggregation of the PI chains due to the steric effects of the Br-substituted dianhydride structure. The PI films exhibited bright green phosphorescence at 512 nm (Φ = 0.02) with a very large Stokes shift of 12 215 cm−1 as well as prompt blue fluorescence at around 408 nm when excited at 315 nm at 298 K. The glass transition and the 5 wt% loss temperatures of DBrBP-PI were 325 °C and 427 °C, respectively. The phosphoresce intensity of the DBrBP-PI film was significantly enhanced under vacuum (Φ = 0.22) and at low temperatures (Φ = 0.76 at 77 K) owing to suppression of triplet state quenching by atmospheric oxygen and dumping of the molecular motions of the PI chains in the solid film. The suggested material design concept shows a way towards creation of stable and efficient down-converters for UV radiation.

Graphical abstract: A colorless semi-aromatic polyimide derived from a sterically hindered bromine-substituted dianhydride exhibiting dual fluorescence and phosphorescence emission

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Publication details

The article was received on 17 Aug 2018, accepted on 19 Oct 2018 and first published on 22 Oct 2018


Article type: Research Article
DOI: 10.1039/C8QM00409A
Citation: Mater. Chem. Front., 2018, Advance Article
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    A colorless semi-aromatic polyimide derived from a sterically hindered bromine-substituted dianhydride exhibiting dual fluorescence and phosphorescence emission

    K. Kanosue, S. Hirata, M. Vacha, R. Augulis, V. Gulbinas, R. Ishige and S. Ando, Mater. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QM00409A

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