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Issue 2, 2019

In situ transformations of Pd/NHC complexes with N-heterocyclic carbene ligands of different nature into colloidal Pd nanoparticles

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Abstract

R–NHC coupling was previously considered as a process of degradation of M/NHC species; however recent studies have pointed out that it may be responsible for the generation of catalytically active NHC-free complexes and/or metallic nanoparticles. Therefore, a detailed and systematic study of R–NHC coupling for various carbene ligands is an important topic. In the present article this process has been studied for reactive aryl iodide coupling partners by a combination of quantum chemical calculations and continuous reaction monitoring via pressurized sample infusion electrospray ionization mass spectrometry (PSI-ESI-MS). DFT calculations revealed a strong tendency of (NHC)Pd(Ph)(I)DMF complexes bearing various N-heterocyclic carbene (NHC) ligands to undergo Ph–NHC coupling. Calculated energy barriers of these reactions lie in the range of 17.9–25.1 kcal mol−1. Ph–NHC coupling is thermodynamically more favorable for the complexes containing unsaturated NHC ligands with bulky substituents. NBO analysis suggests that the process of Ph–NHC formation is similar for different NHC ligands. In order to confirm the results of theoretical studies, a series of ESI-MS reaction monitoring experiments were performed for (NHC)Pd(I)2(Py) and (NHC)Pd(Cl)(η3–1-Ph-C3H4) complexes interacting with iodobenzene, where Ph–NHC coupling products were observed in all cases. As direct experimental evidence, the formation of colloidal Pd-containing nanoparticles was observed in situ for different Pd/NHC complexes in the studied reaction mixtures.

Graphical abstract: In situ transformations of Pd/NHC complexes with N-heterocyclic carbene ligands of different nature into colloidal Pd nanoparticles

Supplementary files

Article information


Submitted
10 Oct 2018
Accepted
05 Dec 2018
First published
06 Dec 2018

Inorg. Chem. Front., 2019,6, 482-492
Article type
Research Article

In situ transformations of Pd/NHC complexes with N-heterocyclic carbene ligands of different nature into colloidal Pd nanoparticles

A. Yu. Kostyukovich, A. M. Tsedilin, E. D. Sushchenko, D. B. Eremin, A. S. Kashin, M. A. Topchiy, A. F. Asachenko, M. S. Nechaev and V. P. Ananikov, Inorg. Chem. Front., 2019, 6, 482 DOI: 10.1039/C8QI01095A

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