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Acetone: a solvent or a reagent depending on the addition order in SET-LRP

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Abstract

Depending on the order of addition to the reaction mixture during biphasic SET-LRP performed in acetone/water mixtures, acetone can serve as a solvent or as a reagent brominated by CuBr2 to provide the electrophilic bromoacetone initiator as well as aldol condensation products.

Graphical abstract: Acetone: a solvent or a reagent depending on the addition order in SET-LRP

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Publication details

The article was received on 13 Sep 2018, accepted on 26 Oct 2018 and first published on 29 Oct 2018


Article type: Communication
DOI: 10.1039/C8PY01331D
Citation: Polym. Chem., 2018, Advance Article
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    Acetone: a solvent or a reagent depending on the addition order in SET-LRP

    A. Moreno, J. Lejnieks, M. Galià, G. Lligadas and V. Percec, Polym. Chem., 2018, Advance Article , DOI: 10.1039/C8PY01331D

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