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Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

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Abstract

A novel octylphosphonic acid (OPA)-catalyzed, high-efficiency, three-component polymerization system involving benzoxazines, odorless isocyanides, and water was developed to synthesize polyamide derivatives with satisfactory molecular weights. This polymerization system showed the advantages of atom-economy, wide substrate scope, short reaction time (6 h), atmosphere-insensitivity, and mild reaction conditions (metal-free catalyst and room temperature).

Graphical abstract: Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

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Publication details

The article was received on 27 Aug 2018, accepted on 01 Nov 2018 and first published on 01 Nov 2018


Article type: Communication
DOI: 10.1039/C8PY01256C
Citation: Polym. Chem., 2018, Advance Article
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    Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

    J. Zhang, W. Shi, Q. Liu, T. Chen, X. Zhou, C. Yang, K. Zhang and Z. Xie, Polym. Chem., 2018, Advance Article , DOI: 10.1039/C8PY01256C

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