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By gradually increasing the length of one linear alkyl substituent from one to seven carbon atoms on the nitrogen atom while keeping another substituent as a methyl group, poly(sulfobetaine methacrylate)s are found to exhibit a wide range of solution behavior in water, ranging from UCST, to totally soluble in water, to LCST, and then insoluble in water.

Graphical abstract: Zwitterionic poly(sulfobetaine methacrylate)s in water: from upper critical solution temperature (UCST) to lower critical solution temperature (LCST) with increasing length of one alkyl substituent on the nitrogen atom

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