Wen-Jing Liang, Jing-Jing Yu, Qi Zhang, Chang-Shun Ma, Zhao-Tao Shi and Da-Hui Qu
Polym. Chem., 2018,9, 4808-4812
DOI:
10.1039/C8PY01070F,
Communication
A novel light-responsive supramolecular polymer was demonstrated from an overcrowded alkene switch (OAS) mounted with two rigid 2-ureido-4-pyrimidinone (UPy) groups. By strong quadruple hydrogen bonding interactions, transOAS-Upy could form well-defined nanospheres in chloroform, which would be transformed into worm-like assemblies after UV irradiation. Moreover, the inverse process of this system could be achieved by exposure to heat.