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Issue 28, 2018
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Stability of Diels–Alder photoadducts in macromolecules

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Abstract

We explore the stability of o-quinodimethane-based ligation points generated by a popular photo-induced Diels–Alder reaction, assessing their ability to withstand challenging environments. Our molecular assessment includes size-exclusion chromatography as well as high resolution electrospray ionization mass spectrometry (SEC-HR ESI MS), finding that their stability is dependent on the macromolecular chain length.

Graphical abstract: Stability of Diels–Alder photoadducts in macromolecules

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Article information


Submitted
18 May 2018
Accepted
25 Jun 2018
First published
25 Jun 2018

Polym. Chem., 2018,9, 3850-3854
Article type
Communication
Author version available

Stability of Diels–Alder photoadducts in macromolecules

C. Petit, L. D. Bangert, M. Abbasi, M. Wilhelm, A. S. Goldmann and C. Barner-Kowollik, Polym. Chem., 2018, 9, 3850
DOI: 10.1039/C8PY00748A

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