Carlton P. Folster and Rebekka S. Klausen
Polym. Chem., 2018,9, 1938-1941
DOI:
10.1039/C8PY00312B,
Communication
Poly(cyclosilane)s, conjugated polymers inspired by crystalline silicon, are synthesized by group 4 metallocene-promoted dehydrocoupling polymerization. Changes in metallocene structure and reactivity are correlated with changes in poly(cyclosilane) chain length and optical properties. This work demonstrates the ability of target-directed synthesis to afford tunable, complex polymeric architectures.