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Issue 7, 2019
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Copper-catalyzed arene amination in pure aqueous ammonia

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Abstract

A simple protocol for copper-catalyzed arene amination using aqueous ammonia without any additional ligands and organic coordinating solvents has been developed. The reaction pathway via a Cu(I)/Cu(III) mechanism is proposed based on the results of control experiments as well as DFT calculations.

Graphical abstract: Copper-catalyzed arene amination in pure aqueous ammonia

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Publication details

The article was received on 31 Oct 2018, accepted on 16 Nov 2018 and first published on 19 Nov 2018


Article type: Communication
DOI: 10.1039/C8OB02708K
Org. Biomol. Chem., 2019,17, 1791-1795

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    Copper-catalyzed arene amination in pure aqueous ammonia

    M. Takagi, A. Watanabe, S. Murata and R. Takita, Org. Biomol. Chem., 2019, 17, 1791
    DOI: 10.1039/C8OB02708K

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