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Issue 7, 2019
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Beyond the traditional roles of Ag in catalysis: the transmetalating ability of organosilver(I) species in Pd-catalysed reactions

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Abstract

Silver salts are one of the most widely used additives in Pd-catalysed transformations. Apart from acting as a halide scavenger and/or an external oxidant, over the past decade it has been revealed that silver salts can play other roles such as a C–H activation promoter or decarboxylating agent, generating organosilver(I) species. These nucleophiles can promote innovative transformations by reacting with PdII intermediates through a transmetalation step. This review article covers different Pd-catalysed C–C bond-forming reactions where silver complexes have been proposed to act as nucleophilic coupling partners. We will also provide relevant mechanistic features associated with these transformations.

Graphical abstract: Beyond the traditional roles of Ag in catalysis: the transmetalating ability of organosilver(i) species in Pd-catalysed reactions

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Publication details

The article was received on 21 Oct 2018, accepted on 17 Nov 2018 and first published on 19 Nov 2018


Article type: Review Article
DOI: 10.1039/C8OB02611D
Citation: Org. Biomol. Chem., 2019,17, 1655-1667

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    Beyond the traditional roles of Ag in catalysis: the transmetalating ability of organosilver(I) species in Pd-catalysed reactions

    Á. L. Mudarra, S. Martínez de Salinas and M. H. Pérez-Temprano, Org. Biomol. Chem., 2019, 17, 1655
    DOI: 10.1039/C8OB02611D

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