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Issue 44, 2018
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A rapid construction of the ABC tricyclic skeleton of malabanone A

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Abstract

The construction of the ABC tricyclic skeleton of malabanone A with the required 4 stereocenters was accomplished in a concise route starting from R-carvone. The synthesis featured an intramolecular [3 + 2] cycloaddition reaction to assemble its A ring and an intramolecular Diels–Alder reaction to construct its C ring.

Graphical abstract: A rapid construction of the ABC tricyclic skeleton of malabanone A

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Publication details

The article was received on 08 Oct 2018, accepted on 24 Oct 2018 and first published on 25 Oct 2018


Article type: Communication
DOI: 10.1039/C8OB02495B
Citation: Org. Biomol. Chem., 2018,16, 8491-8494
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    A rapid construction of the ABC tricyclic skeleton of malabanone A

    T. Li, G. Wu, S. Feng, Z. Wang, X. Xie and X. She, Org. Biomol. Chem., 2018, 16, 8491
    DOI: 10.1039/C8OB02495B

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