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Transition metal-free coupling of terminal alkynes and hypervalent iodine-based alkyne-transfer reagents to access unsymmetrical 1,3-diynes

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Abstract

A variety of unsymmetrical 1,3-diynes can easily be accessed in good yields under catalyst- and transition metal-free conditions by reacting terminal alkynes with hypervalent iodine-based electrophilic alkyne-transfer reagents.

Graphical abstract: Transition metal-free coupling of terminal alkynes and hypervalent iodine-based alkyne-transfer reagents to access unsymmetrical 1,3-diynes

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Publication details

The article was received on 24 Sep 2018, accepted on 01 Oct 2018 and first published on 02 Oct 2018


Article type: Communication
DOI: 10.1039/C8OB02375A
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Transition metal-free coupling of terminal alkynes and hypervalent iodine-based alkyne-transfer reagents to access unsymmetrical 1,3-diynes

    J. Schörgenhumer and M. Waser, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB02375A

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