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Issue 45, 2018
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Nickel-catalyzed regioselective arylation of aromatic amides with aryl iodides enabled by an N,O-bidentate directing group

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Abstract

A bidentate directing group enabled regioselective arylation of C(sp2)–H bonds in aromatic carboxamides with aryl iodides under nickel-catalysis is reported, which provides the corresponding products in moderate to good yields. This protocol using the inexpensive and low-toxic Ni catalyst can tolerate a wide range of functional groups.

Graphical abstract: Nickel-catalyzed regioselective arylation of aromatic amides with aryl iodides enabled by an N,O-bidentate directing group

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Publication details

The article was received on 10 Sep 2018, accepted on 30 Oct 2018 and first published on 30 Oct 2018


Article type: Paper
DOI: 10.1039/C8OB02237B
Citation: Org. Biomol. Chem., 2018,16, 8783-8790
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    Nickel-catalyzed regioselective arylation of aromatic amides with aryl iodides enabled by an N,O-bidentate directing group

    P. Li, G. Wang, H. Chen and L. Wang, Org. Biomol. Chem., 2018, 16, 8783
    DOI: 10.1039/C8OB02237B

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