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Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

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Abstract

A synthesis of the unique bisindole framework present in the mushroom-derived alkaloid sciodole has been achieved, validating a biosynthesis proposal that the C–N bisindole bond present in the natural product is forged by amination of an azafulvenium.

Graphical abstract: Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

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Publication details

The article was received on 31 Aug 2018, accepted on 13 Sep 2018 and first published on 14 Sep 2018


Article type: Communication
DOI: 10.1039/C8OB02142B
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

    J. A. Homer and J. Sperry, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB02142B

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