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Abstract | Cited by

A synthesis of the unique bisindole framework present in the mushroom-derived alkaloid sciodole has been achieved, validating a biosynthesis proposal that the C–N bisindole bond present in the natural product is forged by amination of an azafulvenium.

Graphical abstract: Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

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