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Issue 38, 2018
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Rhodium(III)-catalyzed three-component cascade synthesis of 6H-benzo[c]chromenes through C–H activation

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Abstract

A three-component cascade reaction is described that provides concise access to 6H-benzo[c]chromenes via Rh(III)-catalyzed annulation of aryl ketone O-acyloximes, quinones and acetone. Acetone acts as a co-solvent and as a reactant. This reaction shows high efficiency, atom- and step-economy, good substrate scope, excellent functional group compatibility and gives the products in good yields.

Graphical abstract: Rhodium(iii)-catalyzed three-component cascade synthesis of 6H-benzo[c]chromenes through C–H activation

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Publication details

The article was received on 08 Aug 2018, accepted on 12 Sep 2018 and first published on 13 Sep 2018


Article type: Communication
DOI: 10.1039/C8OB01938J
Citation: Org. Biomol. Chem., 2018,16, 6865-6869
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    Rhodium(III)-catalyzed three-component cascade synthesis of 6H-benzo[c]chromenes through C–H activation

    W. Yang, J. Wang, H. Wang, L. Li, Y. Guan, X. Xu and D. Yu, Org. Biomol. Chem., 2018, 16, 6865
    DOI: 10.1039/C8OB01938J

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