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Issue 43, 2018
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Manganese catalyzed N-alkylation of anilines with alcohols: ligand enabled selectivity

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Abstract

Ligand enabled Earth-abundant manganese catalyzed N-alkylation of amines with alcohols via a hydrogen auto-transfer strategy is reported. The choice of the ligand plays a significant role in the alcohol reactivity (aliphatic or aromatic) toward N-alkylation reactions.

Graphical abstract: Manganese catalyzed N-alkylation of anilines with alcohols: ligand enabled selectivity

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Publication details

The article was received on 03 Aug 2018, accepted on 08 Oct 2018 and first published on 08 Oct 2018


Article type: Paper
DOI: 10.1039/C8OB01886C
Citation: Org. Biomol. Chem., 2018,16, 8175-8180
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    Manganese catalyzed N-alkylation of anilines with alcohols: ligand enabled selectivity

    V. G. Landge, A. Mondal, V. Kumar, A. Nandakumar and E. Balaraman, Org. Biomol. Chem., 2018, 16, 8175
    DOI: 10.1039/C8OB01886C

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