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The chemistry of cyclic imines has been gaining importance in the last decade because of their broad spectrum of applications and biological importance. This review focuses on the synthesis and utilization of these compounds with an emphasis on strategic transformations in organic chemistry. Electron-deficient sulfamate-derived and N-sulfonyl cyclic imines are also discussed as examples of versatile synthons in organic synthesis.

Graphical abstract: Cyclic imines – preparation and application in synthesis

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