Issue 37, 2018
From the journal:

Organic & Biomolecular Chemistry

Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions†

Wen-Hu Bao,a   Chao Wu,a   Jing-Ting Wang,a   Wen Xia,b   Ping Chen,b   Zilong Tang,b   Xinhua Xu ORCID logo c  and  Wei-Min He ORCID logo *ac  

* Corresponding authors

a Hunan Provincial Engineering Research Center for Ginkgo biloba, Hunan University of Science and Engineering, Yongzhou 425100, China

b Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan University of Science and Technology, Xiangtan 411201, China

c State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, China
E-mail: weiminhe2016@yeah.net

Abstract

A simple and practical molecular iodine-mediated method for the efficient construction of thiocarbamates from isocyanides, thiols and water under metal-free and mild conditions has been developed. A variety of thiocarbamates were easily synthesized through this methodology, which has the advantages of simple operation, eco-friendly conditions, good functional group tolerance, and readily accessible raw materials.

Graphical abstract: Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

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Article information

DOI
https://doi.org/10.1039/C8OB01820K
Article type
Paper
Submitted
28 Jul 2018
Accepted
04 Sep 2018
First published
14 Sep 2018

Org. Biomol. Chem., 2018,16, 8403-8407

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Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

W. Bao, C. Wu, J. Wang, W. Xia, P. Chen, Z. Tang, X. Xu and W. He, Org. Biomol. Chem., 2018, 16, 8403 DOI: 10.1039/C8OB01820K

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