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Palladium-catalyzed salt-free double decarboxylative aryl allylation

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Abstract

This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.

Graphical abstract: Palladium-catalyzed salt-free double decarboxylative aryl allylation

  • This article is part of the themed collection: New Talent
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Publication details

The article was received on 26 Jul 2018, accepted on 15 Aug 2018 and first published on 15 Aug 2018


Article type: Communication
DOI: 10.1039/C8OB01806E
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Palladium-catalyzed salt-free double decarboxylative aryl allylation

    R. A. Daley and J. J. Topczewski, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB01806E

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