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Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

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Abstract

A panel of sterically shielded tetrazoles with different N-aryl groups were synthesized and subsequently evaluated in the photoinduced tetrazole–alkene cycloaddition reaction. It was found that increase in the HOMO energy of the corresponding nitrile imines leads to a faster cycloaddition reaction along with a red shift in the fluorescence emission of the pyrazoline cycloadduct.

Graphical abstract: Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

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Publication details

The article was received on 13 Jun 2018, accepted on 03 Jul 2018 and first published on 04 Jul 2018


Article type: Communication
DOI: 10.1039/C8OB01404C
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

    P. An and Q. Lin, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB01404C

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