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Issue 27, 2018
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Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

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Abstract

We report a discovery of a new rimantadine [1-(1-adamantyl)ethanamine]-derived chiral ligand and its application for the preparation of α-amino acids using the second-order asymmetric transformation approach. The operational ease of experimental procedures coupled with excellent chemical yields and stereochemical outcome suggests some potential synthetic generality of this approach.

Graphical abstract: Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

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Article information


Submitted
26 Apr 2018
Accepted
19 Jun 2018
First published
19 Jun 2018

Org. Biomol. Chem., 2018,16, 4968-4972
Article type
Communication

Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

R. Takeda, A. Kawamura, A. Kawashima, T. Sato, H. Moriwaki, K. Izawa, H. Abe and V. A. Soloshonok, Org. Biomol. Chem., 2018, 16, 4968
DOI: 10.1039/C8OB00963E

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