Issue 15, 2018

Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

Abstract

An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.

Graphical abstract: Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

Supplementary files

Article information

Article type
Communication
Submitted
05 Jan 2018
Accepted
13 Mar 2018
First published
14 Mar 2018

Org. Biomol. Chem., 2018,16, 2619-2622

Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

J. Jiang, Y. Hu, X. Cai, L. Wang, Y. Hu, S. Chen, S. Zhang and Y. Zhang, Org. Biomol. Chem., 2018, 16, 2619 DOI: 10.1039/C8OB00033F

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