Jump to main content
Jump to site search


A comparative study of pomegranate Sb@C yolk–shell microspheres as Li and Na-ion battery anodes

Author affiliations

Abstract

Alloy-based nanostructure anodes have the privilege of alleviating the challenges of large volume expansion and improving the cycling stability and rate performance for high energy lithium- and sodium-ion batteries (LIBs and SIBs). Yet, they face the dilemma of worsening the parasitic reactions at the electrode–electrolyte interface and low packing density for the fabrication of practical electrodes. Here, pomegranate Sb@C yolk–shell microspheres were developed as a high-performance anode for LIBs and SIBs with controlled interfacial properties and enhanced packing density. Although the same yolk–shell nanostructure (primary particle size, porosity) and three-dimensional architecture alleviated the volume change induced stress and swelling in both batteries, the SIBs show 99% capacity retention over 200 cycles, much better than the 78% capacity retention of the LIBs. The comparative electrochemical study and X-ray photoelectron spectroscopy characterization revealed that the different SEIs, besides the distinct phase transition mechanism, played a critical role in the divergent cycling performance.

Graphical abstract: A comparative study of pomegranate Sb@C yolk–shell microspheres as Li and Na-ion battery anodes

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Oct 2018, accepted on 15 Nov 2018 and first published on 16 Nov 2018


Article type: Paper
DOI: 10.1039/C8NR08461K
Citation: Nanoscale, 2019, Advance Article
  •   Request permissions

    A comparative study of pomegranate Sb@C yolk–shell microspheres as Li and Na-ion battery anodes

    J. Song, D. Xiao, H. Jia, G. Zhu, M. Engelhard, B. Xiao, S. Feng, D. Li, D. Reed, V. L. Sprenkle, Y. Lin and X. Li, Nanoscale, 2019, Advance Article , DOI: 10.1039/C8NR08461K

Search articles by author

Spotlight

Advertisements