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Gas-Solid Aldol Condensation Reaction in Confined Space of Metal Organic Framework for Formaldehyde Detection

Abstract

Here, a gas-sensitive functional nanomaterial was constructed by confining Tb(acac)3(H2O)2 (acac = acetylacetone) in the space of metal organic framework ZIF-8. This funcional nanometerial can realize a gas-solid state aldol condensation reaction even under room temperature and non-catalyst condition. In the reaction process, formaldehyde (FA) gas molecules can invalide the antenna effect of the acac ligands, which make it as an ultrasensitive FA gas remover and detector (limit of detection value=49ppb)

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Publication details

The article was received on 18 Jul 2018, accepted on 02 Oct 2018 and first published on 02 Oct 2018


Article type: Communication
DOI: 10.1039/C8NR05785K
Citation: Nanoscale, 2018, Accepted Manuscript
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    Gas-Solid Aldol Condensation Reaction in Confined Space of Metal Organic Framework for Formaldehyde Detection

    Q. Wu, M. Nie, Q. Liu, J. Feng, J. Ren, J. zhao and F. Liu, Nanoscale, 2018, Accepted Manuscript , DOI: 10.1039/C8NR05785K

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