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Issue 14, 2018
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A stable layered P3/P2 and spinel intergrowth nanocomposite as a long-life and high-rate cathode for sodium-ion batteries

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Abstract

Layered sodium transition-metal oxides, NaxMeO2, with large theoretical capacity are regarded as an important class of cathode materials for sodium-ion batteries (SIBs). However, they usually exhibit inferior thermodynamic stability and sluggish Na+ kinetics due to the unwanted phase transitions and large Na+-ionic radius. In this work, considering the beneficial synergistic effects of layered P2/P3 and Fd[3 with combining macron]m spinel phases, a stable layered/spinel intergrowth nanocomposite Na0.5[Ni0.2Co0.15Mn0.65]O2 is rationally designed and successfully prepared via a co-precipitation route and a subsequent solid-state reaction, and the triphase synergy in this layered/spinel nanocomposite is demonstrated. In Na/Na0.5[Ni0.2Co0.15Mn0.65]O2 half-cells, it delivers a high specific capacity of ∼180 mA h g−1 and a good cycling stability, with a capacity retention of 87.6% after 100 cycles, at a rate of 0.1C between 1.5 and 4.0 V (vs. Na/Na+). The large reversible capacity of 105 mA h g−1 is also achieved even at a high rate of 10C, indicating high-rate capability. Besides, the full-cells using this nanocomposite as the cathode and hard carbon as the anode exhibit long-term cycle-life and high-power properties, indicating the expected merits of layered/spinel mixed phases. The superior sodium storage performance of this layered P3/P2 and spinel intergrowth nanocomposite makes it a promising candidate as a long-life and high-rate cathode for SIBs.

Graphical abstract: A stable layered P3/P2 and spinel intergrowth nanocomposite as a long-life and high-rate cathode for sodium-ion batteries

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Supplementary files

Article information


Submitted
23 Jan 2018
Accepted
27 Feb 2018
First published
28 Feb 2018

Nanoscale, 2018,10, 6671-6677
Article type
Paper

A stable layered P3/P2 and spinel intergrowth nanocomposite as a long-life and high-rate cathode for sodium-ion batteries

P. Hou, J. Yin, X. Lu, J. Li, Y. Zhao and X. Xu, Nanoscale, 2018, 10, 6671
DOI: 10.1039/C8NR00650D

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