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Self-doped nontoxic red-emitting Mg–N-embedded carbon dots for imaging, Cu(II) sensing and fluorescent ink

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Abstract

Presently, the doping of carbon dots (CD) with heteroatoms and metal-salts as external dopant is a common practice for enhancing its optical efficiency. This approach can involves the use of biomaterials such as plant leaves since they already possess metals inside as an essential element. In this study, the simple process of carbonization of a leaf extract yielded red-emitting magnesium–nitrogen embedded (self-doped) CD, which were denoted as r-Mg–N-CD, possessing a quantum yield value of ∼41%. Importantly, r-Mg–N-CD was proven to be a biocompatible probe based on the bacteriological test performed on two different bacterial strains, Escherichia coli (E. coli) and Proteus vulgaris (P. vulgaris). In addition to the conventional imaging application, r-Mg–N-CD could also be used for the fluorescence-based selective sensing of Cu(II) metal ions among various heavy metals with a detection limit as low as 50 nM and as red-emitting fluorescent ink.

Graphical abstract: Self-doped nontoxic red-emitting Mg–N-embedded carbon dots for imaging, Cu(ii) sensing and fluorescent ink

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Publication details

The article was received on 18 Sep 2018, accepted on 17 Oct 2018 and first published on 18 Oct 2018


Article type: Paper
DOI: 10.1039/C8NJ04754E
Citation: New J. Chem., 2018, Advance Article
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    Self-doped nontoxic red-emitting Mg–N-embedded carbon dots for imaging, Cu(II) sensing and fluorescent ink

    A. Bhati, S. R. Anand, D. Saini, P. Khare, P. Dubey and S. K. Sonkar, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ04754E

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