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Supercritical CO2-assisted deposition of NiO on (101)-anatase-TiO2 for efficient facet engineered photocatalysts

Abstract

NiO/(101)-anatase-TiO2 heretostructure nanoparticles were synthesized by depositing NiO onto the (101) facet of anatase crystals via the supercritical fluid chemical deposition (SFCD) route. Thorough characterizations performed by various techniques (XRD, UV-vis DRS, N2 sorption, HR-TEM, EDX, XPS) indicate that the SFCD method allowed a good dispersion of NiO onto the TiO2 nanoparticles for NiO amount below 2wt%. Compared to pure TiO2, the 0.1-1wt% NiO-TiO2 nanocomposites showed enhanced photocatalytic properties for methylene blue (MB) and methyl orange (MO) decomposition under UV light irridiation, the 0.25wt% NiO-TiO2 system leading to the highest efficiencies. The photocatalytic properties were then rationalized in terms of acidic properties and electronic structure of the NiO-TiO2 nanocomposites. This higher photocatalytic activity was mainly related to the heterocontact at the interface of the NiO-TiO2 crystallites and to enhanced reaction rates at the NiOx surface.

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Publication details

The article was received on 22 Aug 2018, accepted on 08 Oct 2018 and first published on 09 Oct 2018


Article type: Paper
DOI: 10.1039/C8NJ04292F
Citation: New J. Chem., 2018, Accepted Manuscript
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    Supercritical CO2-assisted deposition of NiO on (101)-anatase-TiO2 for efficient facet engineered photocatalysts

    S. Kashiwaya, C. Aymonier, J. Majimel, C. OLIVIER, A. Klein, W. Jaegermann and T. TOUPANCE, New J. Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8NJ04292F

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