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Issue 22, 2018
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Solution behavior and magnetic properties of a novel nonanuclear copper(II) cluster

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Abstract

A novel nonanuclear copper(II) nanocluster (Cu9) was constructed from a well-designed multidentate pyrazole–alcohol ligand and using various small anions. The Cu9 skeleton was found to consist of two similar Cu5 cluster units sharing one central CuII ion and to be protected by the outer organic ligand and auxiliary small anions. The solution behavior of Cu9 was studied in detail by applying the ESI-MS technique. Magnetism analysis implied the presence of antiferromagnetic interactions between the CuII ions.

Graphical abstract: Solution behavior and magnetic properties of a novel nonanuclear copper(ii) cluster

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Publication details

The article was received on 19 Aug 2018, accepted on 02 Oct 2018 and first published on 03 Oct 2018


Article type: Letter
DOI: 10.1039/C8NJ04230F
Citation: New J. Chem., 2018,42, 17884-17888
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    Solution behavior and magnetic properties of a novel nonanuclear copper(II) cluster

    B. Ji, M. Jagodič, H. Ma, H. Su, Y. Li, C. Tung and D. Sun, New J. Chem., 2018, 42, 17884
    DOI: 10.1039/C8NJ04230F

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