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Cascade recognition of Hg2+ and cysteine using a naphthalene based ESIPT sensor and its application in a set/reset memorized device

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Abstract

An optical ESIPT sensor for Hg2+ and cysteine based on a naphthalene platform (1) was designed and synthesized by a one step reaction and characterized by using common spectroscopic techniques. Upon addition of Hg2+ to a 9 : 1 (v/v) aqueous CH3CN (pH 7.0 HEPES buffer) solution of 1, the highly fluorescent probe becomes weakly fluorescent, showing a color change from colorless to dark yellow visible to the naked eye and from fluorescent blue to light yellow when irradiated with 365 nm light. The sensing mechanism has been supported by DFT and 1H NMR titration studies. The in situ generated 1–Hg2+ complex has been used for effectively sensing Cys. Owing to the stronger binding affinity of the sulfhydryl group to Hg2+, Cys can extract Hg2+ from the 1–Hg2+ complex, resulting in the release of 1 and revival of the emission intensity. Sensor 1 has also been successfully applied for the detection of Hg2+ in real water samples with good recovery. The alternate addition of Hg2+ and Cys ions generated “on–off–on” fluorescence cycles, which enabled 1 to be used as a reversible and reconfigurable set/reset memorized device at the molecular level.

Graphical abstract: Cascade recognition of Hg2+ and cysteine using a naphthalene based ESIPT sensor and its application in a set/reset memorized device

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Publication details

The article was received on 03 Aug 2018, accepted on 17 Nov 2018 and first published on 19 Nov 2018


Article type: Paper
DOI: 10.1039/C8NJ03909G
Citation: New J. Chem., 2018, Advance Article
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    Cascade recognition of Hg2+ and cysteine using a naphthalene based ESIPT sensor and its application in a set/reset memorized device

    N. Kaur, G. Jindal, Sukhvinder and S. Kumar, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ03909G

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