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Issue 22, 2018
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Acid- and base-stable porous mechanically interlocked 2D metal–organic polyrotaxane for in situ organochlorine insecticide encapsulation, sensing and removal

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Abstract

A new porous 2D metal–organic polyrotaxane, [Zn2(sdb)2(4-bpdb)]·2DMF (1) 4,4′-sulfonyldibenzoate (sdb), 4-bis(4-pyridyl)-3,4-diaza-1,3-butadiene (4-bpdb), possesses channels that can encapsulate dieldrin in situ and remove it, which is a harmful organochlorine insecticide to form a host–guest system. The pH stability, strong luminescent nature, high sensitivity and complete quenching of 1 in the presence of dieldrin demonstrate its potential as a potential sensor for dieldrin.

Graphical abstract: Acid- and base-stable porous mechanically interlocked 2D metal–organic polyrotaxane for in situ organochlorine insecticide encapsulation, sensing and removal

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Publication details

The article was received on 03 Jul 2018, accepted on 27 Sep 2018 and first published on 27 Sep 2018


Article type: Paper
DOI: 10.1039/C8NJ03302A
Citation: New J. Chem., 2018,42, 18152-18158
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    Acid- and base-stable porous mechanically interlocked 2D metal–organic polyrotaxane for in situ organochlorine insecticide encapsulation, sensing and removal

    P. Abdolalian, A. Morsali, G. Makhloufi and C. Janiak, New J. Chem., 2018, 42, 18152
    DOI: 10.1039/C8NJ03302A

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