BaLiZn3(BO3)3: a new member of the KBe2BO3F2 family possessing dense BO3 triangles and the smallest interlayer distance

Yanna Chen; Min Zhang; Shilie Pan

doi:10.1039/C8NJ02623H

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BaLiZn₃(BO₃)₃: a new member of the KBe₂BO₃F₂ family possessing dense BO₃ triangles and the smallest interlayer distance†

Yanna Chen,^ab Min Zhang

*^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn, zhangmin@ms.xjb.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

BaLiZn₃(BO₃)₃, a new beryllium-free KBe₂BO₃F₂-type borate, features special ²_∞[LiZn₃(BO₃)₃] layers evolved from ²_∞[Be₂BO₃F₂] layers in KBe₂BO₃F₂via substituting BeO₄ with Li/ZnO₄ tetrahedra. The adjacent layers are tightly connected via strong Li/Zn–O covalent bonds, generating dense BO₃ triangles and the smallest interlayer distance among the KBe₂BO₃F₂ derivatives.

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Article information

DOI: https://doi.org/10.1039/C8NJ02623H
Article type: Letter
Submitted: 27 May 2018
Accepted: 29 Jun 2018
First published: 02 Jul 2018

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New J. Chem., 2018,42, 12365-12368

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BaLiZn₃(BO₃)₃: a new member of the KBe₂BO₃F₂ family possessing dense BO₃ triangles and the smallest interlayer distance

Y. Chen, M. Zhang and S. Pan, New J. Chem., 2018, 42, 12365 DOI: 10.1039/C8NJ02623H

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