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Issue 17, 2018
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Preparation of a bispyridine based porous organic polymer as a new platform for Cu(II) catalyst and its use in heterogeneous olefin epoxidation

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Abstract

A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(II). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.

Graphical abstract: Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

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Publication details

The article was received on 06 May 2018, accepted on 23 Jul 2018 and first published on 23 Jul 2018


Article type: Letter
DOI: 10.1039/C8NJ02214C
Citation: New J. Chem., 2018,42, 14067-14070

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    Preparation of a bispyridine based porous organic polymer as a new platform for Cu(II) catalyst and its use in heterogeneous olefin epoxidation

    J. Yi, H. M. Ahn, J. H. Yoon, C. Kim and S. J. Lee, New J. Chem., 2018, 42, 14067
    DOI: 10.1039/C8NJ02214C

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