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Numerical inversion method for improving spatial resolution of elemental imaging by laser ablation-inductively coupled plasma-mass spectrometry

Abstract

To improve the spatial resolution of two-dimensional elemental images in solid organic and inorganic materials, a novel numerical correction method was developed for laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Diffusion and dilution of LA aerosol particles in the carrier gas during transportation from the LA cell to the ICP is the major cause of image diffusion along the axis of a one-dimensional line scan. The correction calculations use (1) numerical forward modelling of the diffused elemental signals and (2) a non-negative signal deconvolution inversion calculation technique to retrieve the original signal profiles. This method improves spatial resolution with a semi-quantitative determination of the ablated masses. We used this method to sharpen spatial distribution images of rhodium particles contained within a meteorite sample.

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Publication details

The article was received on 06 Oct 2017, accepted on 10 Aug 2018 and first published on 10 Aug 2018


Article type: Technical Note
DOI: 10.1039/C7JA00334J
Citation: J. Anal. At. Spectrom., 2018, Accepted Manuscript
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    Numerical inversion method for improving spatial resolution of elemental imaging by laser ablation-inductively coupled plasma-mass spectrometry

    T. Aonishi, T. Hirata, T. Kuwatani, M. Fujimoto, Q. Chang and J. Kimura, J. Anal. At. Spectrom., 2018, Accepted Manuscript , DOI: 10.1039/C7JA00334J

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