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Electrochemical synthesis of tetrazoles via metal- and oxidant-free [3 + 2] cycloaddition of azides with hydrazones

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Abstract

An unprecedented electrochemical [3 + 2] cycloaddition reaction for the synthesis of valuable tetrazoles was developed. Readily available azides and hydrazones were used as the starting materials under simple metal- and oxidant-free reaction conditions. Various functional groups are compatible with this green protocol which can be carried out on a gram-scale or in one pot easily.

Graphical abstract: Electrochemical synthesis of tetrazoles via metal- and oxidant-free [3 + 2] cycloaddition of azides with hydrazones

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Publication details

The article was received on 11 Sep 2018, accepted on 30 Oct 2018 and first published on 31 Oct 2018


Article type: Communication
DOI: 10.1039/C8GC02889C
Citation: Green Chem., 2018, Advance Article
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    Electrochemical synthesis of tetrazoles via metal- and oxidant-free [3 + 2] cycloaddition of azides with hydrazones

    Z. Ye, F. Wang, Y. Li and F. Zhang, Green Chem., 2018, Advance Article , DOI: 10.1039/C8GC02889C

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