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Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system

Abstract

The heterobimetallic ruthenium-cobalt catalytic system exhibited good catalytic performance and reusability in the reductive alkoxycarbonylation of olefins with carbon dioxide. Comparing to the previous system only consisting of ruthenium catalyst, binary catalyst system effectively reduced the usage of noble metal and ionic liquid additive. The respective contribution of ruthenium and cobalt catalysts in this multiple-step catalytic process was investigated by a series of condition-control experiments. The evolution of ruthenium catalyst and the occurrence of alkene hydrogenation during the reaction was explained by theortical calculation.

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Publication details

The article was received on 23 Jul 2018, accepted on 07 Nov 2018 and first published on 08 Nov 2018


Article type: Paper
DOI: 10.1039/C8GC02289E
Citation: Green Chem., 2018, Accepted Manuscript
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    Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system

    X. Zhang, C. Shen, C. Xia, X. Tian and L. He, Green Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8GC02289E

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