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Sustainable Visible light Assisted In-situ Hydrogenation via Magnesium-Water system Catalyzed by Pd-g-C3N4 Photocatalyst

Abstract

A non-hazardous and relatively mild protocol was formulated for an effectual hydrogen generation process via “Magnesium-activated water” system with Pd-g-C3N4 photocatalyst under visible light at room temperature. Water functions photochemically as hydrogen donor without any external source with Pd-g-C3N4 photocatalyst. The synthesized Pd-g-C3N4 photocatalyst is highly efficient under visible light for the selective reduction of wide range of unsaturated derivatives and nitro compounds to afford excellent yields (>99%). The photocatalyst Pd-g-C3N4 could be easily recovered and reused for several runs without any deactivation during the photochemical hydrogen transfer reaction process.

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Publication details

The article was received on 17 Jul 2018, accepted on 24 Oct 2018 and first published on 25 Oct 2018


Article type: Paper
DOI: 10.1039/C8GC02221F
Citation: Green Chem., 2018, Accepted Manuscript
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    Sustainable Visible light Assisted In-situ Hydrogenation via Magnesium-Water system Catalyzed by Pd-g-C3N4 Photocatalyst

    P. Sharma and Y. Sasson, Green Chem., 2018, Accepted Manuscript , DOI: 10.1039/C8GC02221F

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