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Issue 12, 2018
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Selective synthesis of 2,5-bis(aminomethyl)furan via enhancing the catalytic dehydration–hydrogenation of 2,5-diformylfuran dioxime

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Abstract

2,5-Bis(aminomethyl)furan as a promising monomer was efficiently synthesized in 94.1% yield from biomass-derived 2,5-diformylfuran dioxime. The high selectivity is likely to be a result of the controlled reaction pathway over Rh/HZSM-5, which enhanced the sequence of the dehydration–hydrogenation of 2,5-diformylfuran dioxime owing to the surface acidity on the HZSM-5 support.

Graphical abstract: Selective synthesis of 2,5-bis(aminomethyl)furan via enhancing the catalytic dehydration–hydrogenation of 2,5-diformylfuran dioxime

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Article information


Submitted
24 Mar 2018
Accepted
23 Apr 2018
First published
25 Apr 2018

Green Chem., 2018,20, 2697-2701
Article type
Communication

Selective synthesis of 2,5-bis(aminomethyl)furan via enhancing the catalytic dehydration–hydrogenation of 2,5-diformylfuran dioxime

Y. Xu, X. Jia, J. Ma, J. Gao, F. Xia, X. Li and J. Xu, Green Chem., 2018, 20, 2697
DOI: 10.1039/C8GC00947C

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