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Issue 5, 2018
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Template-free and room temperature synthesis of hierarchical porous zeolitic imidazolate framework nanoparticles and their dye and CO2 sorption

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Abstract

Hierarchical porous zeolitic imidazolate framework ZIF-8 nanoparticles have been synthesized using zinc nitrate, 2-methylimidazole (Hmim), and sodium hydroxide. Zinc hydroxide nitrate nanosheets were formed as intermediates that further transformed to hierarchical porous ZIF-8 after the addition of Hmim. These intermediates serve as in situ sacrificial templates and promote the formation of hierarchical porous ZIF-8 without the need for any other templates. The surface area and mesoporosity of the materials can be tuned by adjusting the concentration of NaOH. This method offers a fast and template-free approach for the synthesis of pure hierarchical porous ZIF-8 at room temperature with tunable porosity. The approach has been applied to synthesize two-dimensional ZIF leaf-like materials, ZIF-L. The synthesis of ZIF-8 and ZIF-L can be scaled up with high yields (>80%). The resulting ZIF-8 and ZIF-L materials show very good CO2 sorption properties. ZIF-8 nanoparticles show fast (<5 min), selective, and high efficiency (>95%) uptake of methyl blue in aqueous solution both without and in the presence of other dyes. The results open a new avenue for the understanding of the self-assembly and the formation of hierarchical porous ZIFs.

Graphical abstract: Template-free and room temperature synthesis of hierarchical porous zeolitic imidazolate framework nanoparticles and their dye and CO2 sorption

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Supplementary files

Article information


Submitted
19 Dec 2017
Accepted
23 Jan 2018
First published
12 Feb 2018

Green Chem., 2018,20, 1074-1084
Article type
Paper

Template-free and room temperature synthesis of hierarchical porous zeolitic imidazolate framework nanoparticles and their dye and CO2 sorption

H. N. Abdelhamid and X. Zou, Green Chem., 2018, 20, 1074
DOI: 10.1039/C7GC03805D

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