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Comparison of Advanced Oxidation Processes in the decomposition of diuron and monuron – efficiency, intermediates, Electric Energy per Order and the effect of various matrices

Abstract

The decomposition of diuron and monuron, widely used phenylurea pesticides, via UV-induced photolysis (UV254nm), ozonation (O3), their combination (UV254nm/O3) and heterogeneous photocatalysis (TiO2/UV) were investigated and compared. The UV254nm/O3 and TiO2/UV method proved to be effective from the aspects of both the transformation and the mineralization. The transformation rates changed in the order: O3TiO2/UVUV254nmUV254nm/O3. Comparing the Electric Energy per Order (EEOc) values calculated for the transformation, the most efficient method was UV254nm/O3. However, the lowest EEOTOC value calculated for the mineralization was obtained using TiO2/UV. Identification of the aromatic intermediates revealed that the first step in the decomposition involves transformation of the aliphatic chain, in parallel with dechlorination and hydroxylation of the aromatic ring. The amount and quality of the intermediates formed depends strongly on the method applied. Matrices such as natural waters (from the River Tisza and thermal water from Kistelek) and inorganic salts exert significant effect on the transformation rates only in the case of TiO2/UV. Humic acids behave as “light filter” and consequently decrease the rate of photoinitiated transformation using UV254nm and UV254nm/O3 methods, whereas they slightly enhance the effect of ozonation, most likely because humic acids and/or their intermediates promote the decomposition of ozone and increase the radical concentration. Regarding this parameter, the most sensitive method was heterogeneous photocatalysis, most likely because the well adsorbed humic acid strongly inhibits the formation of hydroxyl radical.

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Publication details

The article was received on 31 Mar 2018, accepted on 31 Jul 2018 and first published on 03 Aug 2018


Article type: Paper
DOI: 10.1039/C8EW00202A
Citation: Environ. Sci.: Water Res. Technol., 2018, Accepted Manuscript
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    Comparison of Advanced Oxidation Processes in the decomposition of diuron and monuron – efficiency, intermediates, Electric Energy per Order and the effect of various matrices

    T. Alapi, J. Farkas, M. Náfrádi, T. Hlogyik, C. P. Bartus, K. Gajda-Schrantz and K. Hernadi, Environ. Sci.: Water Res. Technol., 2018, Accepted Manuscript , DOI: 10.1039/C8EW00202A

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