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Issue 3, 2019
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Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

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Abstract

Structurally flexible oligoisopyrazole molecules were self-assembled into discrete complexes with structural diversity upon palladium coordination. Structural convergence was controlled by a stoichiometry change to induce stepwise metal coordination of isopyrazole subunits. Three different types of complexes were selectively generated from a diisopyrazole ligand. Furthermore, tetraisopyrazole ligands were quantitatively assembled into a discrete complex in a predictable manner.

Graphical abstract: Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

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Supplementary files

Article information


Submitted
15 Dec 2018
Accepted
17 Dec 2018
First published
18 Dec 2018

Dalton Trans., 2019,48, 818-822
Article type
Communication

Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

Y. Ashida, Y. Manabe, S. Yoshioka, T. Yoneda and Y. Inokuma, Dalton Trans., 2019, 48, 818
DOI: 10.1039/C8DT04935A

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