Jump to main content
Jump to site search

Issue 3, 2019
Previous Article Next Article

Thermodynamics of plutonium(III) and curium(III) complexation with a N-donor ligand

Author affiliations

Abstract

The complexation of Pu(III) and Cm(III) with a soft N-donor ligand was investigated using the van't Hoff method, microcalorimetry and DFT calculations. The studies revealed that the strength of the actinide-ligand bond as given by the enthalpic contribution drastically decreases on going from Pu(III) to Cm(III), while the complex stability remains nearly constant.

Graphical abstract: Thermodynamics of plutonium(iii) and curium(iii) complexation with a N-donor ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Nov 2018, accepted on 30 Nov 2018 and first published on 30 Nov 2018


Article type: Communication
DOI: 10.1039/C8DT04671A
Citation: Dalton Trans., 2019,48, 839-842

  •   Request permissions

    Thermodynamics of plutonium(III) and curium(III) complexation with a N-donor ligand

    M. Miguirditchian, D. Guillaumont, A. Saint-Maxent, P. Moisy, D. Guillaneux and C. Madic, Dalton Trans., 2019, 48, 839
    DOI: 10.1039/C8DT04671A

Search articles by author

Spotlight

Advertisements