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Issue 48, 2018
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An unusual cuprous iodide polymer incorporating I, I2 and I3 structural units

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Abstract

A novel cuprous iodide polymer [Cu24-L)(μ2-I)(I2)(I3)]n·nI2 (1, L = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized. 1 contains a 1-D chain [Cu24-L)(μ2-I)(I2)(I3)]n and free I2 molecules, which are interconnected by weak I⋯I interactions to form an unprecedented 3-D cuprous polyiodide network containing rare 1-D [(I)·2I2·(I3)]n polyiodide ribbons. 1 shows luminescence and photoelectronic properties, and its theoretical band structure was also studied.

Graphical abstract: An unusual cuprous iodide polymer incorporating I−, I2 and I3− structural units

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Publication details

The article was received on 16 Oct 2018, accepted on 23 Nov 2018 and first published on 24 Nov 2018


Article type: Communication
DOI: 10.1039/C8DT04150D
Citation: Dalton Trans., 2018,47, 17216-17220
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    An unusual cuprous iodide polymer incorporating I, I2 and I3 structural units

    J. Hu, J. Zhou and S. Cao, Dalton Trans., 2018, 47, 17216
    DOI: 10.1039/C8DT04150D

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