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The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride

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Abstract

Through reactions of 1,2-disila[12]crown-4 or 1,2-disila-benzo[12]crown-4 ethers with BeCl2 eight-membered Be–O-heterocycles, which are annulated by two six-membered Be–O-cycles were obtained and characterised. The reactions leading to these unusual ring systems have been investigated by NMR and IR spectroscopy as well as reactions with further ligand derivatives.

Graphical abstract: The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride

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Publication details

The article was received on 02 Oct 2018, accepted on 11 Oct 2018 and first published on 12 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03963A
Citation: Dalton Trans., 2018, Advance Article
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    The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride

    M. R. Buchner, M. Müller, F. Dankert, K. Reuter and C. von Hänisch, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03963A

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